High resolution spectroscopy for the A (2)A(1) state of CH(3)I(+) by mass-analyzed threshold ionization/photodissociation.
نویسندگان
چکیده
Photodissociation of CH(3)I(+) in the ground vibronic state generated by mass-analyzed threshold ionization resulted in a superb spectrum for the first excited electronic state (A (2)A(1)) with hardly any spurious peak. Rotational structure in the spectrum could be resolved by using a single mode laser. This structure for one vibronic band, 2(1)3(1)6(1), was analyzed with the assumption of Hund's case (a) scheme both in the ground and excited electronic states.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 127 12 شماره
صفحات -
تاریخ انتشار 2007